Estudo de Análise Termogravimétrica de Diferentes Biomassas Lignocelulósicas Utilizando a A análise por Componentes Principais
DOI:
https://doi.org/10.5902/2179460X18332Keywords:
resíduos agro-industriais, resíduos agro-florestais, quimiometria, termogravimetria derivadaAbstract
O comportamento térmico de biomassas lignocelulósicas utilizando a termogravimetria e a termogravimetria derivada são importantes, pois relatam a presença de constituintes químicos, tais como hemicelulose, celulose e lignina. E a utilização de uma análise exploratória multivariada, como a análise por componentes principais (PCA) é útil no sentido de agrupar termogramas com perfis semelhantes. Assim biomassas de capim, café, engaço de banana e açaí com comportamentos semelhantes apresentaram maior degradação térmica atribuída à decomposição da hemicelulose, enquanto que para a decomposição da celulose as amostras de arroz, serragem e soja. Observa-se que todas as dez amostras de biomassa exibem tendência semelhante de perda de peso associada à decomposição da lignina.
Downloads
References
ASTM E 1655-00. Standard Practices for Infrared Multivariate Quantitative Analysis; 2005.
Jeguirim, M.; Bikaia, J.; Elmaya, Y.; Limousya, L.; Njeugna,E.Thermal characterization and pyrolysis kinetics of tropical biomass feedstocks for energy recovery. Energy Sustain. Dev. 2014;23: 188–193.
Parthasarathy, P.; Narayanan, K.S.; Arockiam, L. Study on kinetic parameters of different biomass samples using thermo-gravimetric analysis. Biomass Bioenerg. 2013;58:58-66.
Chen, Z. et al. Characteristics and kinetic study on pyrolysis of five lignocellulosic biomass via thermogravimetric analysis. Bioresour. Technol. 2015; doi: http://dx.doi.org/10.1016/j.biortch.2015.05.062.
Saldarriaga, J, F.; Aguado, R.; Pablos, A.; Amutio, M.; Olazar, M.; Bilbao, J. Fast characterization of biomass fuels by thermogravimetric analysis (TGA). Fuel, 2015;140:744–75.
Limayem, A.; Ricke, S.C. Lignocellulosic biomass for bioethanol production: Current perspectives, potential issues and future prospects. Prog. Energ. Combust. 2012;38:449-467.
Raveendran, K.; Ganesh A.; Khilar, K.C. Pyrolysis characteristics of biomass and biomass components. Fuel, 1996;75: 987-98.
Yang, H.; Yan, R.; Chin, T.; Liang, D.T.; Chen, H.; Zheng, C. Thermogravimetric analysis-Fourier transform infrared analysis of palm oil waste pyrolysis. Energ. Fuel, 2004;18:1814-1821.
Tomczak, F.; Sydenstricker, T.H.D.; Satyanarayana, K.G. Studies on lignocellulosic fibers of Brazil. Part II: Morphology and properties of Brazilian coconut fibers. Composites: Part A. 2007;38:1710-1721.
Rambo, M.K.D.; Amorim, E.P.; Ferreira, M.M.C. Potential of visible-near infrared spectroscopy combined with chemometrics for analysis of some constituents of coffee and banana residues. Anal. Chim. Acta, 2013;775:41-49.
Rambo, M.K.D.; Ferreira, M.M.C. Determination of Cellulose Crystallinity of Banana Residues Using Near Infrared Spectroscopy and Multivariate Analysis. J. Braz. Chem. Soc. 2015a;1-9.doi: http://dx.doi.org/10.5935/01035053.20150118
Rambo, M.K.D.; Schmidt, F.; Ferreira, M.M.C. Characterization of Brazilian biomass sources for biorefinery opportunities. Talanta. (2015b) Doi:
Brereton, R. G. Chemometrics: Applications of Mathematics and Statistics to Laboratory Systems, Ellis Horwood, Chichester, 1993.
Wold, S.; Esbensen, K.; Geladi, P. Principal Component Analysis. Chem. Intell. Lab. Syst. 1987; 2:37-52.
Guimarães, J. L.; Frollinni, E.; Silva, C.G.; Wypych, F.; Satyanarayana, K.G. Characterization of banana, sugarcane bagasse and sponge gourd fibers of Brazil. Ind. Crop Prod. 2009;30:407–415.
Downloads
Published
How to Cite
Issue
Section
License
To access the DECLARATION AND TRANSFER OF COPYRIGHT AUTHOR’S DECLARATION AND COPYRIGHT LICENSE click here.
Ethical Guidelines for Journal Publication
The Ciência e Natura journal is committed to ensuring ethics in publication and quality of articles.
Conformance to standards of ethical behavior is therefore expected of all parties involved: Authors, Editors, Reviewers, and the Publisher.
In particular,
Authors: Authors should present an objective discussion of the significance of research work as well as sufficient detail and references to permit others to replicate the experiments. Fraudulent or knowingly inaccurate statements constitute unethical behavior and are unacceptable. Review Articles should also be objective, comprehensive, and accurate accounts of the state of the art. The Authors should ensure that their work is entirely original works, and if the work and/or words of others have been used, this has been appropriately acknowledged. Plagiarism in all its forms constitutes unethical publishing behavior and is unacceptable. Submitting the same manuscript to more than one journal concurrently constitutes unethical publishing behavior and is unacceptable. Authors should not submit articles describing essentially the same research to more than one journal. The corresponding Author should ensure that there is a full consensus of all Co-authors in approving the final version of the paper and its submission for publication.
Editors: Editors should evaluate manuscripts exclusively on the basis of their academic merit. An Editor must not use unpublished information in the editor's own research without the express written consent of the Author. Editors should take reasonable responsive measures when ethical complaints have been presented concerning a submitted manuscript or published paper.
Reviewers: Any manuscripts received for review must be treated as confidential documents. Privileged information or ideas obtained through peer review must be kept confidential and not used for personal advantage. Reviewers should be conducted objectively, and observations should be formulated clearly with supporting arguments, so that Authors can use them for improving the paper. Any selected Reviewer who feels unqualified to review the research reported in a manuscript or knows that its prompt review will be impossible should notify the Editor and excuse himself from the review process. Reviewers should not consider manuscripts in which they have conflicts of interest resulting from competitive, collaborative, or other relationships or connections with any of the authors, companies, or institutions connected to the papers.