Comparative study of the chemical components of Pinus taeda wood in kraft pulping

Authors

DOI:

https://doi.org/10.5902/1980509893109

Keywords:

Chemical components, Cellulose yield, Pulp quality

Abstract

This study aimed to produce kraft pulps from Pinus taeda wood and evaluated the efficiency of the pulping process based on pulp quality, considering the chemical composition of its components. Industrial wood chips of P. taeda, approximately 16 years old, from commercial plantations of a pulp and paper company in Santa Catarina, Brazil, were used. The chips were classified manually to eliminate oversized ones with the aid of a sieve, and subsequently eliminate knots and fines. For the chemical analyses of the wood, part of the chips was converted into sawdust using a Willey-type mill. The kraft pulping was carried out in a 20-liter capacity electrically heated rotary laboratory digester (Regmed). The physicochemical analyses of the wood and brown kraft pulp included: moisture, ash, total extractives, lignin, holocellulose, and alpha-cellulose. The contents of chemical components (extractives, Klason lignin, holocellulose, alpha-cellulose, and ash) retained in the pulp and removed from the wood during cooking were determined. P. taeda wood presented chemical characteristics favorable for kraft pulp production, notably due to its low contents of total extractives (3.76%) and lignin (27.76%) and its high carbohydrate content (holocellulose de 59.61% e alpha-cellulose de 50.66%). Furthermore, its potential use as raw material for brown kraft pulp production is evident.

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Author Biographies

Diesley Olga Homercher Machado Vedovotto, Universidade Federal de Santa Maria

Forestry Engineer

Daniel Tavares de Farias, Universidade Federal de Santa Maria

Forestry Engineer, PhD student in Forestry Engineering

Roberta Rodrigues Roubuste, Universidade Federal de Santa Maria

Forestry Engineer, PhD student in Forestry Engineering

', Universidade Federal de Santa Maria

Forestry Engineer, Master's student in Forestry Engineering

Dieimes Maciel da Silva, Universidade Federal de Santa Maria

Student in Forestry Engineering

Cyndel Ramos Monteiro, Universidade Federal de Santa Maria

Student in Forestry Engineering

Mikaela Rehbein, Universidade Federal de Santa Catarina

Student in Forestry Engineering

Eduardo Schmitt, Universidade Federal de Santa Maria

Student in Forestry Engineering

Rodrigo Coldebella, Universidade Federal de Santa Maria

Forestry Engineer, Doctor in Forestry Engineering

Cristiane Pedrazzi, Universidade Federal de Santa Maria

Forestry Engineer, Doctor in Forestry Sciences, Professor

References

ALONSO-ESTEBAN, J. I.; CAROCHO, M.; BARROS, D.; VELHO, M. V.; HELENO, S.; BARROS, L. Chemical Composition and Industrial Applications of Maritime Pine (Pinus Pinaster Ait.) Bark and Other Non-Wood Parts. Reviews in Environmental Science and Bio/Technology, v. 21, n. 3, p. 583–633, set. 2022. DOI: https://doi.org/10.1007/s11157-022-09624-1

BERROCAL, A.; BAEZA, J.; RODRÍGUEZ, J.; ESPINOSA, M.; FREER, J. EFFECT OF TREE AGE ON VARIATION OF PINUS RADIATA D. DON CHEMICAL COMPOSITION. Journal of the Chilean Chemical Society, v. 49, n. 3, set. 2004. DOI: https://doi.org/10.4067/S0717-97072004000300012

COELHO, M. U.; DA SILVA, JR., F. G.; MILAGRES, F. R.; SOMMER, S. M.; DO AMARAL, C. A. S.; BIERNASKI, F. A. Technological Evaluation of Pinus Maximinoi Wood for Industrial Use in Kraft Pulp Production. TAPPI Journal, v. 20, n. 8, p. 501–508, 1 set. 2021. DOI: https://doi.org/10.32964/TJ20.8.501

COLODETTE, J. L. Notas de aula de química da madeira.

DIAS, A.; CARVALHO, A.; SILVA, M. E.; LIMA-BRITO, J.; GASPAR, M. J.; ALVES, A.; RODRIGUES, J. C.; PEREIRA, F.; MORAIS, J.; LOUSADA, J. L. Physical, Chemical and Mechanical Wood Properties of Pinus Nigra Growing in Portugal. Annals of Forest Science, v. 77, n. 3, p. 72, set. 2020. DOI: https://doi.org/10.1007/s13595-020-00984-8

DIAS, O. A.; SIMONELLI, G. Qualidade da madeira para a produção de celulose e papel. Enciclopédia Biosfera, v. 9, n. 17, p. 3632-3642, dez. 2013.

FERNANDES, M. A. M.; NÖRNBERG, L. V.; SANTOS, O. P. D.; PIMENTEL, N.; QUEVEDO, F. F.; CARDOSO, G. V.; MOREIRA, M. L. Qualidade da madeira de híbridos de Corymbia para a produção de celulose kraft. Ciência Florestal, p. e87028, 27 fev. 2025. DOI: https://doi.org/10.5902/1980509887028

FIROUZABADI, M. D.; TATARI, A. SO2-Ethanol–Water (SEW) and Kraft Pulp and Paper Properties of Eldar Pine (Pinus Eldarica): A Comparison Study. Biomass Conversion and Biorefinery, v. 14, n. 13, p. 14745–14753, jul. 2024. DOI: https://doi.org/10.1007/s13399-023-03785-x

IBÁ. Relatório anual IBÁ 2024: Indústria Brasileira de Árvores. 2024.

IGLESIAS, Maria C. et al. Pulping processes and their effects on cellulose fibers and nanofibrillated cellulose properties: A review. Forest Products Journal, v. 70, n. 1, p. 10-21, 2020. DOI: https://doi.org/10.13073/FPJ-D-19-00038

LUZ, C. E. A.; BARELLA, R. A.; MARTINS, A. S.; DE CASTRO, P. J.; PINI, A. INTELIGÊNCIA ARTIFICIAL APLICADA À PREDIÇÃO DO KAPPA NO PROCESSO DE COZIMENTO KRAFT. O Papel, v. 85, p. 77–81, 2024.

MANOEL, G. F.; RIBEIRO, C. S.; DE REZENDE, D. B.; CARDOSO, M.; GONÇALVES, L. M. RHEOLOGY OF EUCALYPTUS AND PINE KRAFT BLACK LIQUOR. ARACÊ, v. 6, n. 4, p. 14732–14751, 13 dez. 2024. DOI: https://doi.org/10.56238/arev6n4-218

MATTOS, B. D.; LOURENÇON, T. V.; GATTO, D. A.; SERRANO, L.; LABIDI, J. Chemical Characterization of Wood and Extractives of Fast-Growing Schizolobium Parahyba and Pinus Taeda. Wood Material Science & Engineering, v. 11, n. 4, p. 209–216, 7 ago. 2016. DOI: https://doi.org/10.1080/17480272.2014.970574

MBOOWA, D. A Review of the Traditional Pulping Methods and the Recent Improvements in the Pulping Processes. Biomass Conversion and Biorefinery, v. 14, n. 1, p. 1–12, jan. 2024. DOI: https://doi.org/10.1007/s13399-020-01243-6

PRZYBYSZ BUZAŁA, K.; KALINOWSKA, H.; MAŁACHOWSKA, E.; BORUSZEWSKI, P.; KRAJEWSKI, K.; PRZYBYSZ, P. The Effect of Lignin Content in Birch and Beech Kraft Cellulosic Pulps on Simple Sugar Yields from the Enzymatic Hydrolysis of Cellulose. Energies, v. 12, n. 15, p. 2952, 31 jul. 2019. DOI: https://doi.org/10.3390/en12152952

RAMOS, R. D.; LONGUE JUNIOR, D.; GOMES, F. J. B.; MEDEIROS, N. C. G. Influência da densidade básica e da composição química da madeira para a indústria de polpa celulósica: um estudo de caso. Ciência Florestal, v. 34, n. 3, e85566, jul./set. 2024. DOI: https://doi.org/10.5902/1980509885566

SANTOS, J.; PEREIRA, J.; FERREIRA, N.; PAIVA, N.; FERRA, J.; MAGALHÃES, F. D.; MARTINS, J. M.; DULYANSKA, Y.; CARVALHO, L. H. Valorisation of Non-Timber by-Products from Maritime Pine (Pinus Pinaster, Ait) for Particleboard Production. Industrial Crops and Products, v. 168, p. 113581, set. 2021. DOI: https://doi.org/10.1016/j.indcrop.2021.113581

SJOSTROM, E. Wood Chemistry: Fundamentals and Applications. Academic Press, 1993.

TAPPI 210 CM. TECHNICAL ASSOCIATION OF THE PULP AND PAPER INDUSTRY. 1997.

TAPPI 211 OM-93. TAPPI test methods T211 om-93. Em: TECHNICAL ASSOCIATION OF THE PULP AND PAPER INDUSTRY. 1997.

TAPPI T203 CM-99. TAPPI test methods T264 om-88: “preparation of wood for chemical analysis”. Em: T203: Alpha-, Beta-and Gamma-Cellulose in Pulp. 1997.

TAPPI T204 CM-85. T204 cm-85: Solvent extractives of wood and pulp. Em: TECHNICAL ASSOCIATION OF THE PULP AND PAPER INDUSTRY. 1997.

TAPPI T222 OM-98. T222: acid-insoluble lignin in wood and pulp. TECHNICAL ASSOCIATION OF THE PULP AND PAPER INDUSTRY. Em: TECHNICAL ASSOCIATION OF THE PULP AND PAPER INDUSTRY. 1997.

TUNCER, F. D.; KARTAL, S. N.; SOYTÜRK, E. E.; ARANGO, R. A.; OHNO, K. M.; ÖNSES, M. S.; ÇELIK, N.; IBANEZ, C. M. Changes in Chemical Properties and Microstructure of Pinus Taeda and Eucalyptus Bosistoana Woods Modified by Contact Charring. European Journal of Wood and Wood Products, v. 82, n. 1, p. 107–121, fev. 2024. DOI: https://doi.org/10.1007/s00107-023-02011-9

VIDRANO, B. R. A.; GOMES, F. J. B.; PEDRAZZI, C.; BALDIN, T.; DENARDI, L.; ALMEIDA, D. P. de. INFLUENCIA DA ALTURA DA ÁRVORE NAS CARACTERISTICAS DAS MADEIRAS DE Pinus taeda L. E Pinus patula Schltdl & Cham. Em: O Meio Ambiente Sustentável. [s.l: s.n.]p. 118–129. DOI: https://doi.org/10.22533/at.ed.5951920129

VIVIAN, M. A.; FOGLIATTO, M. M.; BONFATTI JÚNIOR, E. A.; MODES, K. S.; PEDRAZZI, C.; CORRÊA, R. Efeito da carga alcalina nos parâmetros de polpação da madeira de Cryptomeria japonica. Ciência Florestal, v. 32, n. 2, p. 939–958, 24 jun. 2022. DOI: https://doi.org/10.5902/1980509863579

VIVIAN, M. A.; MODES, K. S.; CAETANO, A. P. Potencial da madeira de Pinus glabra para produção de polpa celulósica. Madera y Bosques, v. 26, n. 3, 16 dez. 2020. DOI: https://doi.org/10.21829/myb.2020.2632058

VIVIAN, M. A.; NETO, O. R.; DUARTE, G. A.; PAES, S. T. D. S.; MOREIRA, L. M.; MODES, K. S.; SILVA JÚNIOR, F. G. D.; DOBNER JÚNIOR, M. Qualidade da madeira de Podocarpus lambertii visando à produção de polpa celulósica de fibra longa. Revista de Ciências Agroveterinárias, v. 23, n. 3, p. 473–482, 4 out. 2024. DOI: https://doi.org/10.5965/223811712332024473

WISE, L., E.; MAXINE, M.; D’ADDIECOA, A. D. A. A CHLORITE HOLOCELLULOSE, ITS FRACTIONATION AND BEARING ON SUMMATIVE WOOD ANALYSIS AND STUDIES ON THE HEMICELLULOSES. Chlorite holocellulose, its fractionation and bearing on summative wood analysis and studies on the hemicelluloses, Paper Trade Journal. p. 35–43, 1946.

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Published

2026-02-27

How to Cite

Vedovotto, D. O. H. M., Farias, D. T. de, Roubuste, R. R., Wanessa Lunardi, Silva, D. M. da, Monteiro, C. R., Rehbein, M., Schmitt, E., Coldebella, R., & Pedrazzi, C. (2026). Comparative study of the chemical components of Pinus taeda wood in kraft pulping. Ciência Florestal, 36, e93109. https://doi.org/10.5902/1980509893109

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