Optimization of Pb2+, Cd2+, Ni2+ and Ba2+ adsorption onto light expanded clay aggregate (LECA)

Authors

DOI:

https://doi.org/10.5902/2179460X68809

Keywords:

Adsorption, Toxic Metals, Light Expanded Clay Aggregate

Abstract

The possibility of Pb2+, Cd2+, Ni2+ and Ba2+ ions removal from aqueous solution using light expanded clay aggregate (LECA) was investigated in this work. The central composite design (CCD) in response surface methodology (RSM) was used to optimize the operating parameters (adsorbent granulometry, absorption time and initial metal ions concentration) to reach the maximum ions removal in single and multi-elemental solutions. After optimization, the results shows that the removal efficiency decrease following the ion sequence Pb2+ > Ba2+ > Cd2+ > Ni2+ ions. The better efficiency (~95%) is observed for the Pb2+. The Langmuir and Freundlich isotherm models were applied to the equilibrium data at room temperature. The results revealed that data on LECA was very well fitted with Langmuir equations. The real interest of this work is to demonstrate that a simple material such as LECA can be used to remove extremely small levels of toxic metals, such as those found in drinking water. So our results could be the starting point for the development of a low-cost filtration system to remove toxic metals.

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Author Biographies

Helen Sandra de Sousa Laet Mundim, Universidade Federal do Triângulo Mineiro, Uberaba, MG

Master’s in Environmental Science and Technology.

Brunno Borges Canelhas, Instituto Federal do Triângulo Mineiro, Uberaba, MG

Professor, PhD in Chemistry.

Fausto de Souza Pagan, Universidade Federal do Triângulo Mineiro, Uberaba, MG, Brazil

Master’s in Chemistry

Júlio Cesar de Sousa Inácio Gonçalves, Universidade Federal do Triângulo Mineiro, Uberaba, MG

Professor, PhD in Science (Hydraulics and Sanitation).

Mário Sérgio da Luz, Universidade Federal do Triângulo Mineiro, Uberaba, MG

Graduated in Chemical Engineering from the Faculdade de Engenharia Química de Lorena. Master in Materials Engineering from the Faculdade de Engenharia Química de Lorena. PhD from the Faculdade de Engenharia de Lorena - USP with emphasis on Materials Engineering. Postdoctoral at the Montana State University - USA and at the Universidade de São Paulo. Professor at the Federal Universidade Federal do Triângulo Mineiro.

Deusmaque Carneiro Ferreira, Universidade Federal do Triângulo Mineiro, Uberaba, MG

Professor, PhD in Chemistry

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Published

2022-04-04 — Updated on 2022-04-12

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How to Cite

Mundim, H. S. de S. L., Canelhas, B. B., Pagan, F. de S., Gonçalves, J. C. de S. I., Luz, M. S. da ., & Ferreira, D. C. (2022). Optimization of Pb2+, Cd2+, Ni2+ and Ba2+ adsorption onto light expanded clay aggregate (LECA) . Ciência E Natura, 44, e3. https://doi.org/10.5902/2179460X68809 (Original work published April 4, 2022)

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