Study of adsorption capacity of commercial activated carbon <i>versus</i> storage time

Authors

DOI:

https://doi.org/10.5902/1980509838092

Keywords:

Charcoal, Iodine index, Moisture, Expiration date

Abstract

The pulverized activated carbon, when well packed and stored, doesn't have either a regulated or approved shelf life. In general, this expiration date is determined based on the established requirements coming from the manufacturer itself and it is directly related to an overestimation of the time that the product is held in the customer storage location until its use. In this analysis, the research has assessed the efficiency of the moistened and the dry activated carbon powder, relating parameters of adsorption capacity (numbers of iodine and humidity) in these materials with time information. The charcoals containing alkaline surface didn’t exhibit a variation in the parameters evaluated along the storage time, since they didn’t feature statistical significance, once the Fregression < Fcritical and the rate of p > 0.05, both for dry and wet basis. From the viewed acid carbons (with corrected pH), there was only one which got sensitive to moisture and iodine adsorptions over time. From the equation of the line originated by analysis of regression for this charcoal, the following correlation was obtained: Iodine Index=824-0.370 days, showing that the storage time for the carbon was equal to 605 days, assuring that the right value of iodine index is equivalent to the limit of 600 mg I2 g-1 carbon.

Downloads

Download data is not yet available.

Author Biographies

Helen Caroline Valter Fischer, Universidade Estadual do Centro-Oeste - UNICENTRO, Guarapuava, PR

Departamento de Química

Setor de Ciências Exatas e de Tecnologia

Maria Lurdes Felsner, Universidade Estadual do Centro-Oeste - UNICENTRO, Guarapuava, PR

Departamento de Química

Setor de Ciências Exatas e de Tecnologia

Sueli Percio Quinaia, Universidade Estadual do Centro-Oeste - UNICENTRO, Guarapuava, PR

Departamento de Química

Setor de Ciências Exatas e de Tecnologia

References

ABNT. ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. Carvão ativado pulverizado – Determinação do número de iodo – MB-3410. Rio de Janeiro, 1991a.

ABNT. ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. MB-3414: Carvão ativado pulverizado – determinação da umidade. Rio de Janeiro, 1991b.

ABNT. ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. Carvão ativado pulverizado – Especificação – EB-2133. Rio de Janeiro, 1991c.

ALLEN, S. J.; WHITTEN, L. The Production and Characterisation of Activated Carbons: A Review. Developments in Chemical Engineering and Mineral Processing, [s.l.], v. 6, n. 5, p. 231-261, 1998.

AWWA. Standart for Activated Carbon. ANSI/AWWAB600-96. 1996. Denver, Colorado.

DE ARRUDA, E.L.; DE ANDRADE, A. M.; JÚNIOR, A.F.D. Produção e ativação do carvão vegetal de três espécies florestais. Floresta, v. 47, n. 3, 2017.

DEIANA, A. C. et al. Use of grape must as a binder to obtain activated carbon briquettes. Brazilian Journal Chemical Engineering, [s.l.], v. 21, n. 4, p. 585-591, 2004.

EATON, A.D. et al. Standard methods for the examination of water and wastewater. American public health association, [s.l.], v. 21, p. 1600, 2005.

HUNG, Y. et al. Granular Activated Carbon Adsorption in: Physicochemical Treatment Processes. P. 573-633, Humana Press Inc. 2005. DOI. https://doi.org/10.1385/159259820x.

ISO. International Organization for Standardization. ISO 10523:2008, Water quality - Determination of pH. 2008. https://www.iso.org/standard/51994.html.

KOSAKA, Koji et al. Removal of radioactive iodine and cesium in water purification processes after an explosion at a nuclear power plant due to the Great East Japan Earthquake. Water research, [s.l.], v. 46, n. 14, p. 4397-4404, 2012.

LIMA, L. S. et al. Characterization of activated carbons from different sources and the simultaneous adsorption of Cu, Cr, and Zn from metallurgic effluent. Separation and Purification Technology, [s.l.], v. 122, p. 421–430, 2014.

MORENO-CASTILLA, C. Adsorption of organic molecules from aqueous solutions on carbon materials. Carbon, [s.l.], v. 42, p. 83–94, 2004.

SHAMSUDDINA, M.S.; YUSOFFA, N.R.N.; SULAIMAN, M.A. Synthesis and characterization of activated carbon produced from kenaf core fiber using H3PO4 activation. Procedia Chemistry, [s.l.], v. 19, p. 558 – 565, 2016.

WEST, K. Carbon chemistry. Chelsea House Publishers. USA. 117 p. 2008.

YAKOUT, S.M.; SHARAF EL-DEEN, G. Characterization of activated carbon prepared by phosphoric acid activation of olive stones. Arabian Journal of Chemistry, [s.l.], v.9, p. S1155–S1162, 2016.

Published

2019-09-30

How to Cite

Fischer, H. C. V., Lima, L. S. de, Felsner, M. L., & Quinaia, S. P. (2019). Study of adsorption capacity of commercial activated carbon <i>versus</i> storage time. Ciência Florestal, 29(3), 1090–1099. https://doi.org/10.5902/1980509838092

Issue

Section

Articles