Evaluation of the degradation potential of different advanced oxidation processes for a textile dye mixture: a kinetic study with mathematical modeling and toxicological tests

Authors

DOI:

https://doi.org/10.5902/2179460X39776

Keywords:

ANN, Descoloration, Photodegradation, Treatment

Abstract

Studies and research have been developed around the world on environmental pollution. Among the most diverse types of pollutants, textile dyes have attracted attention in the Brazilian Northeast. These compounds, besides being persistent, resist to the conventional treatments applied in the wastewater treatment plants. Thus, the present study evaluated the degradation of the mixture of direct red 23, direct red 227 and direct orange 26 dyes by advanced oxidation processes (AOPs). It was observed that the homogeneous AOPs were more efficient, being able to degrade 100% of the chromophoric groups after the optimization of the variables [H2O2], [Fe] and pH. The reaction kinetics for the photo-Fenton process followed a pseudo-first order non-linear model, with rapid decay of the concentrations in the first 60 min. Aiming to have a methodology capable of predicting the degradation efficiency for the studied processes, it was verified that the artificial neural networks MLP 4-9-3 and MLP 5-6-3 well represent the data from the homogeneous and heterogeneous processes, respectively. A toxicity study was carried out using seeds, bacteria and microcrustaceans and it was found that the intermediate compounds formed during the treatment process act differently for each of them.

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Author Biographies

Joanna Cysneiros Silva, Universidade Federal de Pernambuco, Recife, PE

Mestrado em Engenharia Química na Universidade Federal de Pernambuco (2018). Atualmente é técnica de operação na empresa Petróleo Brasileiro S/A. 

Rayany Magali da Rocha Santana, Universidade Federal de Pernambuco, Recife, PE

Aluna de mestrado do Programa de Pós-graduação em Engenharia Química da Universidade Federal de Pernambuco, desenvolvendo pesquisas sobre tratamento de corantes, empregando processos oxidativos avançados. 

Graziele Elisandra do Nascimento, Universidade Federal de Pernambuco, Recife, PE

Pesquisadora e aluna de pós-doutorado do Programa de Pós-Graduação em Engenharia Química da Universidade Federal de Pernambuco, com bolsa de fixação de pesquisador pela Fundação de Amparo a Ciência e Tecnologia de Pernambuco. 

Alex Leandro Andrade de Lucena, Universidade Federal de Pernambuco, Recife, PE

Aluno de doutorado em Engenharia Química pela Universidade Federal de Pernambuco. 

Ana Maria Ribeiro Bastos da Silva, Universidade Federal de Pernambuco, Recife, PE

Técnica de laboratório da Universidade Federal de Pernambuco.

José Luís Ferreira Sá, Universidade Federal de Pernambuco, Recife, PE

Doutorando do curso de Pós-graduação em Bioquímica e Fisiologia na Universidade Federal de Pernambuco

Ana Maria Mendonça de Albuquerque Melo, Universidade Federal de Pernambuco, Recife, PE

Professora associada 4 da Universidade Federal de Pernambuco.

Daniella Carla Napoleão, Universidade Federal de Pernambuco, Recife, PE

Professora Adjunta AII da Universidade Federal de Pernambuco

Marta Maria Menezes Bezerra Duarte, Universidade Federal de Pernambuco, Recife, PE

Professora do Departamento de Engenharia Química da Universidade Federal de Pernambuco

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Published

2020-09-03

How to Cite

Silva, J. C., Santana, R. M. da R., Nascimento, G. E. do, Lucena, A. L. A. de, Silva, A. M. R. B. da, Sá, J. L. F., Melo, A. M. M. de A., Napoleão, D. C., & Duarte, M. M. M. B. (2020). Evaluation of the degradation potential of different advanced oxidation processes for a textile dye mixture: a kinetic study with mathematical modeling and toxicological tests. Ciência E Natura, 42, e7. https://doi.org/10.5902/2179460X39776

Issue

Vol. 42 (2020): 40 years special anniversary edition

Section

40 YEARS - Anniversary Special Edition

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