Titanium dioxide immobilization in recycled aluminum net for degradation of textile dye by Heterogeneous Photocatalysis trough neural networks
DOI:
https://doi.org/10.5902/2236117037718Schlagworte:
Aluminum net, Advanced oxidation process, Remazol golden yellow, Photocatalysis, PhytotoxicityAbstract
In this work, aluminum net crafted (recycled) were used as TiO2 support for the treatment of textile dye Remazol golden yellow (RGY 150). The immobilization of 200mg of TiO2 was accomplished after aluminum net calcination. The following experiments were carried out in a photocatalytic bench reactor: preliminary tests, a 23 factorial experimental design with best system and the degradation kinetic in systems with TiO2 supported on aluminum net.It was observed characteristic peaks of aluminum and TiO2 (anatase and rutile) by XRD and the catalyst film formation was verified by SEM. The system UV/H2O2/TiO2 performed higher efficiency, with 99% of dye degradation in 50 minutes, followed by the system UV/H2O2/TiO2sp with 93% of dye degradation. Whereas the supported catalyst presents execution advantages and high degradation rates, the factorial design was realized for this system, displaying best degradation (100% degradation in 35 minutes). It was obtained k = 0.114 min-1 and R² = 0.994 in a pseudo-first-order model adjustment system. The use of artificial neural network was proven to be efficient to predict the degradation of a textile dye, with an absolute error of 0.0181. After treatment, there was a decrease of dye toxicity.
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AJMAL, A.; MAJEED, I.; MALIK, R. N.; IQBAL, M.; NADEEM, M. A.; HUSSAIN, I.; NADEEM, M. A. Photocatalytic degradation of textile dyes on Cu2O-CuO/TiO2anatase powders. Journal of Environmental Chemical Engineering, v. 4, p. 2138–2146, 2016.
ALINSAFI, A.; EVENOU, F.; ABDULKARIM, E. M.; PONS, M. N.; ZAHRAA, O.; BENHAMMOU, A.; NEJMEDDINE, A. Treatment of textile industry wastewater by supported photocatalysis. Dyes and Pigments, v. 74, p. 439–445, 2007.
ASGHAR, A.; RAMAN, A. A. A.; DAUD, W. M. A. W. Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: A review. Journal of Cleaner Production, v. 87, p. 826–838, 2015.
BARROS, A. L.; DOMINGOS, A. A. Q.; FECHINE, P. B. A.; KEUKELEIRE, D.; NASCIMENTO, R. F. PET as a Support Material for TiO2 in Advanced Oxidation Processes. Journal Applied Polymer Science, v. 131, p. 1-9, 2014.
BORGES, S.S.; XAVIER, L.P.S.; SILVA, A.C.; AQUINO, S.F. Immobilized titanium dioxide (TiO2) in different support materials to use in heterogeneous photocatalysis. Química Nova, v. 39, p. 836-844, 2016.
CUNHA, D. L.; KUZNETSOV, A.; ACHETE, C. A.; MACHADO, A. E. H.; MARQUES, M. Immobilized TiO2 on glass spheres applied to heterogeneous photocatalysis: photoactivity, leaching and regeneration process. PeerJ, v. 6, p. 4464-4483, 2018.
DAS, L.; MAITY, U.; BASU, J. K. The photocatalytic degradation of carbamazepine and prediction by artificial neural networks. Process Safety and Environmental Protection, v. 92, p. 888-895, 2014.
DELNAVAZ, M; AYATI, B.; GANJIDOUST, H.; SANJABI, S. Application of concrete surfaces as novel substrate for immobilization of TiO2nano powder in photocatalytic treatment of phenolic water. Journal of Environmental Health Science and Engineering, v. 13, p. 58-68, 2015.
ERJAVEC, B.; HUDOKLIN, P.; PERC, K.; TIŠLER, T.; DOLENC, M. S.; PINTAR, A. Glass fiber-supported TiO2photocatalyst: Efficient mineralization and removal of toxicity/estrogenicity of bisphenol A and its analogs. Applied Catalysis B:
Environmental, v. 183, p. 149–158, 2016.
ALALM, M. G; TAWFIK, A.; OOKAWARA, S. Enhancement of photocatalytic activity of TiO2 by immobilization on activated carbon for degradation of pharmaceuticals. Journal of Environmental Chemical Engineering, v. 4, p. 1929–1937, 2016.
GIROTO, J. A.; GUARDANI, R.; TEIXEIRA, A. C. S. C.; NASCIMENTO, C. A. O. Study on the photo-Fenton degradation of polyvinyl alcohol in aqueous solution. Chemical Engineering and Processing, v. 45, p. 523-532, 2006.
GÖB, S.; OLIVEROS, E.; BOSSMANN, S. H.; BRAUN, A. M.; GUARDANI, R.; NASCIMENTO, C. A. O. Modeling the kinetics of a photochemical water treatment process by means of artificial neural networks. Chemical Engineering and Processing, v. 38, p. 373-382, 1999.
GUPTA, V. K.; JAIN, R.; NAYAK, A.; AGARWAL, S.; SHRIVASTAVA, M. Removal of the hazardous dye Tartrazine by photodegradation on titanium dioxide surface. Materials Science and Engineering: C, v. 31, p. 1062–1067, 2011.
HAIKIN, S. Neural Networks: A Comprehensive Foundation, 1. ed. Delhi, India: Pearson Education, 1999. 482 p.
HASSAAN, M. A.; NEMR, A. E. Health and Environmental Impacts of Dyes: Mini Review. American Journal of Environmental Science and Engineering, v. 1, p. 64-67, 2017.
KENNEDY, J.; EBERHART, R. Particle swarm optimization. IEEE International Conference (1995).
KUMAR, M. S.; SONAWANE, S. H.; BHANVASE, B. A.; BETHI, B. Treatment of ternary dye wastewater by hydrodynamic cavitation combined with other advanced oxidation processes (AOP’s). Journal of Water Process Engineering, v. 23, p. 250–256, 2018.
LI, F.; HUANG, J.; XIA, Q.;LOU, M.;YANG, B.;TIAN, Q.;LIU, Y. Direct contact membrane distillation for the treatment of industrial dyeing wastewater and characteristic pollutants. Separation and Purification Technology, v. 195, p. 83-91, 2018.
LUDWICHK, R.; HELFERICH, O. K.; KIST, C. P.; LOPES, A. C.; CAVASOTTO, T.; SILVA, D. C.; BARRETO-RODRIGUES, M. Characterization and photocatalytic treatability of red water from Brazilian TNT industry. Journal of Hazardous Materials, v. 293, p. 81–86, 2015.
M’BRA, C. I.; GARCÍA-MUÑOZ, P.; DROGUI, P.; KELLER, N.; TROKOUREY, A.; ROBERT, D. Heterogeneous photodegradation of Pyrimethanil and its commercial formulation with TiO2 immobilized on SiC foams. Journal of Photochemistry and Photobiology A: Chemistry, v. 368, p. 1–6, 2019.
MEYER, B.; FERRIGNI, N.; PUTNAM, J.; JACOBSEN, L.; NICHOLS, D.; MCLAUGHLIN, J. Brine Shrimp: A Convenient General Bioassay for Active Plant Constituents. PlantaMedica, v. 45, p. 31–34, 1982.
MOREIRA, F. C.; BOAVENTURA, R. A. R.; BRILLAS, E.; VILAR, V. J. P. Electrochemical advanced oxidation processes: A review on their application to synthetic and real wastewaters. Applied Catalysis B: Environmental, v. 202, p. 217-261, 2017.
MOZIA, S.; BROZEK, P.; PRZEPIORSKI, J.; TRYBA, B.; MORAWSKI, A. W. Immobilized TiO2 for Phenol Degradation in a Pilot-Scale Photocatalytic Reactor. Journal of Nanomaterials, v. 2012, p. 1-10, 2012.
MUKHERJEE, D.; BARGHI, S.; RAY, A. Preparation and characterization of the TiO2 immobilized polymeric photocatalyst for degradation of aspirin under UV and Solar Light. Processes, v. 2, p. 12-23, 2014.
NASCIMENTO JÚNIOR, W. J.; ROCHA, O. R. S.; DANTAS, R. F.; SILVA, J. P.; BARBOSA, A. A. Kinetic study of food dyes removal from aqueous solutions by solar heterogeneous photocatalysis with artificial neural networks and phytotoxicity assessment. Desalination and Water Treatment, v. 104, p. 304–314, 2018.
OANCEA, P.; MELTZER, V. Photo-Fenton process for the degradation of Tartrazine (E102) in aqueous medium. Journal of the Taiwan Institute of Chemical Engineers, v. 44, p. 990–994, 2013.
OBLAK, R.; KETE, M.; TASBIHI, M. Alternative support materials for titaniaphotocatalyst towards degradation of organic pollutants. Journal of Water Process Engineering, v. 23, p. 142–150, 2018.
PAJOOTAN, E.; RAHIMDOKHT, M.; ARAMI, M. Carbon and CNT fabricated carbon substrates for TiO2 nanoparticles immobilization with industrial perspective of continuous photocatalytic elimination of dye molecules. Journal of Industrial and Engineering Chemistry, v. 55, p. 149–163, 2017.
POURAKBAR, M.; MOUSSAVI, G.; SHEKOOHIYAN, S. Homogenous VUV advanced oxidation process for enhanced degradation and mineralization of antibiotics in contaminated water. Ecotoxicology and Environmental Safety, v. 125, p. 72–77, 2016.
RAMASUNDARAM, S., SON, A., SEID, M. G., SHIM, S., LEE, S. H., CHUNG, Y. C, HONG, S. W. Photocatalytic applications of paper-like poly(vinylidene fluoride)–titanium dioxide hybrids fabricated using a combination of electrospinning and electrospraying. Journal of Hazardous Materials, v. 285, p. 267–276, 2015.
REZA, K. M., KURNY, A., GULSHAN, F. Parameters affecting the photocatalytic degradation of dyes using TiO2: a review. Applied Water Science, v. 7, p. 1569–1578, 2017.
ROCHA, O. R. S.; DANTAS, R. F.; NASCIMENTO JÚNIOR, W. J.; FUJIWARA, Y.; DUARTE, M. M. M. B.; SILVA, J. P. Kinetic study and modelling of cephalexin removal from aqueous solution by advanced oxidation processes through artificial neural networks. Desalination and Water Treatment, v. 92, p. 72-79, 2017.
ROSTAMI-VARTOONI, A.; NASROLLAHZADEH, M.; SALAVATI-NIASARI, M.; ATAROD, M. Photocatalytic degradation of azo dyes by titanium dioxide supported silver nanoparticles prepared by a green method using Carpobrotus acinaciformis extract. Journal of Alloys and Compounds, v. 689, p. 15–20, 2016.
ROZAS, O.; VIDAL, C.; BAEZA. C.; JARDIM, W. F.; ROSSNER, A.; MANSILLA, H. D. Organic micropollutants (OMPs) in natural waters: Oxidation by UV/H2O2 treatment and toxicity assessment. Water Research, v. 98, p. 109-118, 2016.
SALAEH, S.; JURETIC PERISIC, D.; BIOSIC, M.; KUSIC, H.; BABIC, S.; LAVRENCIC STANGAR, U.; DIONYSIOU, D. D.; LONCARIC BOZIC, A. Diclofenac removal by simulated solar assisted photocatalysis using TiO2-based zeolite catalyst; mechanisms, pathways and environmental aspects. Chemical Engineering Journal, v. 304, p. 289–302, 2016.
SANTOS, M. M. D. M.; DUARTE, M. M. M. B.; NASCIMENTO, G. E.; SOUZA, N. B. G.; ROCHA, O. R. S. Use of TiO2 photocatalyst supported on residues of polystyrene packaging and its applicability on the removal of food dyes. Environmental Technology, p. 1–14, 2018.
SOLEYMANI, A. R.; CHAHARDOLI, R.; KAYKHAII, M. Development of UV/H2O2/TiO2 –LECA hybrid process based on operating cost: Application of an effective fixed bed photo-catalytic recycled reactor. Journal of Industrial and Engineering Chemistry, v. 44, p. 90–98, 2016.
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